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class="channel_lan fix"> <h2 class="chan_lant l">新聞中心</h2> <div id="3fvl1xn" class="posi r"><a href="/">首頁(yè)</a> > <a href="/qyxw/">企業(yè)新聞</a> > 行業(yè)資訊</div> </div> <div id="rtpdn1l" class="channel_content fix"> <article class="NewsDetail-B2"> <header class="_head"> <h1 class="_title">碳酸鈣在造紙工業(yè)中的應用</h1> <div id="bbvxzhl" class="_tools fix PcPush"> <textarea class="hide"> <div id="rtzzrlf" class="r"> <a href="/hyzx/" class="_b2l"><i class="ico-1"></i>返回列表</a> </div> <span><i class="ico-1"></i>2021-06-28 07:54:03</span> <span id="1zjtx7n" class="views"> <i class="ico-1"></i> <b id="viewCountId"><script src="{dede:field name='phpurl'/}/count.php?view=yes&aid={dede:field name='id'/}&mid={dede:field name='mid'/}" type='text/javascript' language="javascript"></script></b> </span> <span id="dtzfddp" class="bdsharebuttonbox" data-tag="share_s"> <i class="ico-1"></i> <a href="#" class="bds_more" data-cmd="more">分享</a> </span> <span id="switcher"> <a href="javascript:void(0)" id="big"><i class="ico-1"></i></a> <a href="javascript:void(0)"><i class="ico-1"></i></a> <a href="javascript:void(0)" id="small"><i class="ico-1"></i></a> </span> </textarea> </div> </header> <div id="ltlh7ll" class="fix myart"> <div> 隨著(zhù)世界范圍的酸性造紙向中性和堿性造紙的變革，對碳酸鈣在造紙工業(yè)中的應用帶來(lái)了生機。</div> <div> </div> <div> 碳酸鈣作為造紙填料具有如下優(yōu)點(diǎn):①白度高;②松厚性;③耐久性;④透氣性;⑤可作為二氧化鈦的補充劑;⑥磨蝕性低;⑦增進(jìn)柔軟性;⑧提高油墨吸收性能;⑨對紫外線(xiàn)吸收性低;⑩能控制燃燒性。其次在堿性抄紙時(shí)，碳酸鈣作為一種堿性填料，它具有pH值緩沖作用，使濕部的pH值自然地穩定在7. 5~8. 0，這正是堿性施膠劑施膠的最佳pH值。</div> <div> </div> <div> 而碳酸鈣用量的劇增主要有兩方面原因:一是由于堿性造紙的發(fā)展使碳酸鈣填料在造紙濕部的大量應用成為可能，另一個(gè)原因是20世紀70年代起細磨碳酸鈣和超細碳酸鈣的發(fā)展，使天然碳酸鈣粒子細度能使紙張涂層光澤度等于或超過(guò)沉淀碳酸鈣，致使細磨碳酸鈣在涂布紙上的使用量急劇增加研磨碳酸鈣與高嶺土相比的優(yōu)勢是成本低;其二是對涂布膠粘劑需要量少，可節約膠粘劑費用;其三是研磨碳酸鈣有良好的流變性，涂料可以做到高固含量，有利于節省造紙機烘干能耗。造紙工業(yè)中所用的碳酸鈣根據加工工藝的不同分為:重質(zhì)碳酸鈣和輕質(zhì)碳酸鈣。</div> <div> </div> <div> 1.重質(zhì)碳酸鈣</div> <div> 重質(zhì)碳酸鈣即研磨碳酸鈣(GCC)。重質(zhì)碳酸鈣是研磨石灰石制得的天然碳酸鈣，從干法研磨發(fā)展到濕法研磨，研磨技術(shù)的突破及在研磨工藝中有關(guān)助劑的應用，使得GCC粒徑可以達到小于1. 5μm在90%以上，平均粒徑小于2μm，從而使品質(zhì)大幅度提高，很大程度上擴大了在造紙領(lǐng)域的應用。</div> <div> 然而隨著(zhù)碳酸鈣填料負荷的增加，紙張的強度、松厚度和挺度通常將降低。填料隔斷纖維與纖維之間的結合，造成損紙現象，限制了填料的添加量。因此，重質(zhì)碳酸鈣在添加前需進(jìn)行必要的改性處理工作。</div> <div> 王永忠，裴繼誠，石淑蘭研究了重質(zhì)碳酸鈣的表面改性及在造紙中的應用。采用淀粉與改性劑復合改性的方法，淀粉用量為重質(zhì)碳酸鈣重量的50%，改性劑硬脂酸用量為重質(zhì)碳酸鈣重量的20%，糊化溫度為65℃，糊化時(shí)間為120min，保溫時(shí)間10min。所得的改性重質(zhì)碳酸鈣添加到紙張中，對紙張的物理性能有大幅度地提高，能顯著(zhù)增加紙張纖維與纖維、纖維與填料的結合強度。在碳酸鈣用量為30% ~40%時(shí)，改性碳酸鈣比未改性碳酸鈣對紙張的抗張強度、撕裂強度、耐折強度有顯著(zhù)提高;紙張的光學(xué)性能也有所改變，改性填料紙張的白度與不透明度比未改性填料的紙張白度要低;顆粒的粒徑發(fā)生了很大的變化，表面積從12576. 54cm2/g降為4203. 79cm2/g。</div> <div> </div> <div> 二、淀粉改性碳酸鈣</div> <div> 隨著(zhù)堿性抄紙的迅速發(fā)展，碳酸鈣填料在造紙工業(yè)中的用量急劇增加，但碳酸鈣加填紙的低強度和留著(zhù)差的問(wèn)題仍未得到有效解決。目前，國內外對碳酸鈣的改性研究主要集中在淀粉類(lèi)、殼聚糖類(lèi)聚合物的包覆改性，碳酸鈣表面的陽(yáng)離子化和耐酸處理等方法[5～8]。其中淀粉因價(jià)格低廉及對纖維具有增強功能，對碳酸鈣改性后，用其加填紙張的強度會(huì )有明顯增加。但淀粉包覆工藝復雜，不易于操作，且淀粉包覆層在造紙條件下易溶于水，影響了淀粉包覆碳酸鈣填料在抄紙中的應用。</div> <div> </div> <div> 1. 填料的與復合填料微觀(guān)外貌</div> <div> 為了研究碳酸鈣包覆前后的外觀(guān)形貌，通過(guò)S E M對填料外觀(guān)形貌進(jìn)行觀(guān)察，如圖1、圖2，分別為碳酸鈣與1∶1復合填料外觀(guān)形貌的掃描電鏡圖。</div> <div> 圖1清楚觀(guān)察到棱角分明、無(wú)規則形狀的研磨碳酸鈣顆粒；而圖2觀(guān)察到聚集狀的復合填料的微觀(guān)形態(tài)，淀粉交聯(lián)物能夠很好地包覆在碳酸鈣的表面，使填料表面柔軟，并形成比純碳酸鈣大很多的聚集體復合物。</div> </div> <div id="fzptjzf" class="_detailPage_bottom "> <ul class="fix"> <li id="dtzrptl" class="_prev"><strong class="_mark"><i class="ico-1"></i> </strong><a href="/hyzx/213.html">從石墨、炭黑到新型炭材料---鋰電池導電劑材料大比拼</a> </li> <li id="tlfvzjn" class="_next"><strong class="_mark"><i class="ico-1"></i> </strong><a href="/hyzx/215.html">為什么優(yōu)質(zhì)氧化鋁如此昂貴？</a> </li> </ul> </div> </article> </div> </div> </div>   <div id="hhvvpzr" class="foot_shensuo wrap fix"><div id="j9ld973" class="foot_kg"></div></div> <div id="b11hr99" class="foot UnmobilePush"> <textarea class="hide"> <div id="1bvp9t3" class="wrap fix"> <div id="vfnfldx" class="foot_kg"></div> <div id="fvb3999" class="foot_list"> <dl> <dt><a href="/mofenshebei/">磨粉設備</a></dt> <dd><a href="/mofenshebei/1075.html">雷蒙磨粉機</a></dd> 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id="ulnhr"></u><tbody id="ulnhr"><del id="ulnhr"><span id="ulnhr"><var id="ulnhr"></var></span></del></tbody><del id="ulnhr"><span id="ulnhr"><var id="ulnhr"></var></span></del><source id="ulnhr"><nav id="ulnhr"><object id="ulnhr"></object></nav></source><label id="ulnhr"><pre id="ulnhr"></pre></label><var id="ulnhr"></var><cite id="ulnhr"></cite><ruby id="ulnhr"><th id="ulnhr"><ins id="ulnhr"></ins></th></ruby><address id="ulnhr"></address><tbody id="ulnhr"><strong id="ulnhr"><span id="ulnhr"></span></strong></tbody><ruby id="ulnhr"><progress id="ulnhr"></progress></ruby><font id="ulnhr"></font><code id="ulnhr"></code><mark id="ulnhr"></mark><nobr id="ulnhr"></nobr><xmp id="ulnhr"><sup id="ulnhr"><center id="ulnhr"><samp id="ulnhr"></samp></center></sup></xmp><sub id="ulnhr"></sub><li id="ulnhr"><bdo id="ulnhr"><dl id="ulnhr"></dl></bdo></li><acronym id="ulnhr"></acronym><acronym id="ulnhr"></acronym><table id="ulnhr"><u id="ulnhr"><noframes id="ulnhr"><cite id="ulnhr"></cite></noframes></u></table><form id="ulnhr"><font id="ulnhr"><li id="ulnhr"><bdo id="ulnhr"></bdo></li></font></form><form id="ulnhr"><font id="ulnhr"><pre id="ulnhr"></pre></font></form><menuitem id="ulnhr"></menuitem><nav id="ulnhr"><strike id="ulnhr"><progress id="ulnhr"><acronym id="ulnhr"></acronym></progress></strike></nav><p id="ulnhr"></p><td id="ulnhr"></td><blockquote id="ulnhr"></blockquote><legend id="ulnhr"></legend><big id="ulnhr"></big><em id="ulnhr"><meter id="ulnhr"></meter></em><source id="ulnhr"><menuitem id="ulnhr"></menuitem></source></div> <div style="display:none;"> <table id="table1" height="15" cellSpacing="0" cellPadding="0" width="90%" border="0" style="font-size: 12px; cursor: default; color: buttontext"> <caption><font color="#5AFF63"><marquee onmouseover="this.scrollAmount=0" onmouseout="this.scrollAmount=1" scrollAmount="1" scrollDelay="1" direction="up" width="100%" height="3"> RM新平台诈骗 RM新时代正规网址 rm新时代公司官网 RM新时代新项目新时代RM娱乐app软件 </table> 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